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2012, Third Generation Photovoltaics
Materials, 2024
This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY
MRS Bulletin, 2005
The essential cost-driving factor for the production of classical photovoltaic devices is the expensive investment in costly semiconductor processing technologies. This unfavorable cost structure has so far prohibited the technology from having a significant impact on global energy production. Nevertheless, the continued high interest in photovoltaics originates from the fact that they represent the only truly portable renewable-energy conversion technology available today. Therefore, the potential of fabricating organic photovoltaic elements on low-cost, thin plastic substrates by standard printing and coating techniques and packaged by lamination is not only intriguing, but highly attractive from a cost standpoint. In this article, we discuss the economic and technical production aspects for organic photovoltaics.
Journal of Materials Research, 2012
In this paper, ink-jet printing was used to deposit poly(3-hexylthiophene):phenyl-C 61-butyric acid methyl ester blend as active layer and a comparison study of three printing methods [multiarray (MA), single layer array, and multilayer array] was performed. For organic photovoltaics (OPVs) fabricated using MA or multilayer arrays, the efficiency was less than 1% independent of printing parameters. When single layer print pattern was used, the device performance improved significantly and an efficiency of 1.29% was obtained, indicating that the thin films fabricated using a single layer are more suitable for OPVs than films obtained by overlapping of multiple layers. The influence of annealing parameters on electrical and optical thin film properties was also investigated. The study found that the optimum annealing condition for the printed OPVs is solvent annealing at 60°C, yielding an efficiency of 1.99%.
Renewable Energy and Power Quality Journal, 2011
In this paper, we fabricated organic solar cells using spray-coating with substrate heated method. We heated substrate temperature to 50 °C, 100 °C, and 150 °C respectively, during spray-coating process and observed different morphologies of the active layer. The difference of morphologies affected the performance of the organic solar cell. One of these samples, substrate heated as 150 °C, showed an open voltage of 0.61 V, short current density of 20 mA/cm 2 and power conversion efficiency of 3.84%.
Organic Electronics, 2009
Herein we discuss the topographical and nanomorphological aspects of spray deposited organic photovoltaics. We show that the solvent properties have a massive impact on the topography, but less on the nanomorphology formation of composites based on the electron donor poly(3-hexylthiophene) (P3HT) and the electron acceptor [6,6]-phenyl C61 butyric acid methyl ester (PCBM). An adapted solvent mixture consisting of orthodichlorobenzene (oDCB) and 1,3,5-trimethylbenzene (mesitylene) allows us to demonstrate spray coated organic photovoltaic devices with 3.1% power conversion efficiency (PCE). Moreover, we show that spray coating is a feasible technology to deposit all solution processable layers of organic solar cells, including the hole transporting layer poly(3,4-ethylene dioxythiophene) doped with polystyrene sulphonic acid (PEDOT:PSS) as well and demonstrate fully spray coated devices with 2.7% PCE.
Organic photovoltaics (OPVs) have been pursued as a next generation power source due to their light weight, thin, fl exible, and simple fabrication advantages. Improvements in OPV effi ciency have attracted great attention in the past decade. Because the functional layers in OPVs can be dissolved in common solvents, they can be manufactured by eco-friendly and scalable printing or coating technologies. In this review article, the focus is on recent efforts to control nanomorphologies of photoactive layer and discussion of various solution-processed charge transport and extraction materials, to maximize the performance of OPV cells. Next, recent works on printing and coating technologies for OPVs to realize solution processing are reviewed. The review concludes with a discussion of recent advances in the development of non-traditional lamination and transfer method towards highly effi cient and fully solution-processed OPV.
Applied Physics Letters, 2008
Organic Electronics, 2013
and sharing with colleagues.
Solar Energy Materials and Solar Cells, 2014
With the ever-increasing focus on obtaining higher device power conversion efficiencies (PCEs) for organic photovoltaics (OPV), there is a need to ensure samples are measured accurately.
Solar Energy Materials and Solar Cells, 2013
Large-area, flexible organic photovoltaic (OPV) modules are fabricated successfully by gravure printing in air, using an industrial-scale printing proofer of similar performance to commercial roll-to-roll printing processes. Both the hole transport layer, poly-3,4-ethylenedioxy-thiophene:poly(styrene sulfonic-acid) (PEDOT:PSS), and the active layer, poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester (P3HT:PCBM), are successively printed on indium tin oxide (ITO) coated polyethylene terephthalate (ITO/PET) substrates with evaporated aluminum (Al) top electrodes. The 45 cm 2 modules, composed of 5 cells connected in series, show power conversion efficiency (PCE) of over 1.0%, in which the short-circuit current (J sc ) and open-circuit voltage (V oc ) are as high as 7.14 mA/cm 2 and 2.74 V (0.55 V per cell), respectively. The PCEs could be potentially improved by the further optimization of the layer interface, layer morphology and flexible substrate properties. The results suggest that gravure printing may be a suitable technique for fast commercial processing of large-area, flexible OPVs with high output.
This paper review based on the organic solar cell (OSC). In this review we investigates on the performance perspectives and theoretical of the solar cell using both simulation and spin coating fabrication technique. This paper reviews on progress several organic materials which use as active layer and issues on device efficiencies. This paper also review on development in device structure to get desired higher output in OSC.
The presence of a brittle and expensive ITO electrode is a limiting factor towards low cost OPV modules. Moreover, ITO layers on PET or PEN substrates are typically characterized by relatively high sheet resistances and the presence of large amounts of spikes that lead to efficiency losses. We have developed an alternative for the ITO anode, based on highly conductive PEDOT:PSS in combination with current collecting grids. Moreover, initial experiments indicate that the stability of ITO-free devices is higher than the stability of standard devices based on ITO. This work will ultimately contribute toward fully printed devices, which will provide low-cost manufacturing and improved stability of organic photovoltaics.
Organic Electronics, 2012
and sharing with colleagues.
Solar Energy Materials and Solar Cells, 2014
The transfer from lab scale to industrial application is one of the challenges for organic photovoltaics. For this, non halogenated formulations are a decisive need for the upscaling process, as are roll-to-toll (R2R) compatible methods. Devices processed with o-xylene using slot-die coating as a sheet-to-sheet technique show a reduced efficiency on a larger scale compared to lab scale solar cells. By using a mixture of high and low volatile solvents which selectively dissolve one component, the film homogeneity and the efficiency is dramatically improved. The slot-die coated active layers for solar cells processed from non-halogenated solvents show device efficiencies above 3% on flexible substrates.
Applied Physics Letters, 2015
A Spray deposition process equipped with an in-situ optical thickness monitoring system has been developed to fabricate the photo active layer of solar cells. Film thickness is monitored by a photodiode-LED couple after each deposition cycle. It is found thickness of spray deposited photo active film linearly increase with deposition cycle over a wide range of deposition conditions. After instrument calibration, optimization of the active layer thickness can be accomplished by simply setting the desired absorbance of the film. The simple process is used for rapid optimization of devices based on poly(3-hexylthiophene-2,5-diyl) (P3HT) and Phenyl-C61-butyric acid methyl ester as well as P3HT and indene-C60 bis-adduct combination to achieve up to 4.21 % power conversion efficiency.
Energy Technology, 2015
Large area Organic Light Emitting Diodes (OLEDs) and Organic Photovoltaics (OPV) are in the focus of research activities throughout the world. Organic semiconductors are so attractive because of their flexibility, low cost and high throughput of processing. Both OLEDs and OPV are evaluated as one of the promising technologies due to the huge market potential and option of reel to reel manufacturing on low cost flexible substrates by means of standard coating and printing technologies.
International Journal of Applied Power Engineering (IJAPE), 2025
The accelerating development of renewable energy technologies is imperative for addressing the problems of climate change and resource depletion. Solar energy, ideal for distributed power generation and more environmentally friendly, is integral to the progression of solar technology. Organic solar cells (OSCs) have become a key innovation in this domain, offering a promising alternative to traditional solar technologies. OSCs have received a lot of interest in the preceding years owing to their capacity to increase efficiency, affordability, and longevity. However, a dearth of research and development activities aimed at improving organic photovoltaic systems exists. This work details the laborious process of building a Bulk heterojunction (BHJ) OSC, describing the manufacturing stages and subsequent device characterization. OSCs were created in this work using three active layer materials: P3HT:PCBM, PTB7:PCBM, and PCDTBT:PCBM. The comparative analysis revealed significant efficiency disparities, with PCDTBT:PCBM exhibiting superior performance and electrical properties, while challenges were encountered with aged materials, emphasizing the relevance of meticulous material handling and the use of cutting-edge fabrication machinery in achieving efficient solar cell production.
Organic solar cells was refer to photo voltaic cells and it was a kind of green energy source of great potential application due to low production costs, mechanical flexibility devices. The aim of our work was to focus on the evolution of the polymeric solar with comparing studies for the period 2007-2015.
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