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2015, Journal of Nanoparticles
Dodecyl benzene sulfonic acid (DBSA) doped polyaniline (PANI-DBSA) has been synthesized by chemical oxidative polymerization of aniline monomer in the presence of DBSA. The UV-visible spectroscopy and X-ray diffraction measurements confirm the formation of PANI and its doping by DBSA. SEM images show the formation of submicron size rod shaped PANI particles. A vibrating capacitor based ammonia gas sensor was prepared by spin coating PANI-DBSA film over copper (Cu) substrate. The sensor exploited Kelvin probe technique to monitor contact potential difference between PANI and Cu as a function of time and ammonia concentration. Upon exposure to 30 ppm ammonia, the sensor displays response time of 329 s, recovery time of 3600 s, and sensitivity value of 1.54 along with good repeatability.
2017
In the present research effort, we account for the acquisition of room temperature ammonia gas sensor based on polyaniline (PANI) nanoparticles. The polyaniline thin film was deposited on porous silicon substrate using the spin coating method. PANI nanofilms were characterized for their structural as well as surface morphologies. The XRD analysis showed partially crystalline nature polyaniline thin film. The Ammonia gas sensing response of PANI was obtained for different concentration of ammonia (50, 100, 200, 300, 400, 500 and 600 ppm). The sensitivity of PANI was observed to increase with the increase in the concentration of ammonia.
IEEE Access
Dodecyl benzene sulphonic acid (DBSA) doped polyaniline (PANI) nanorods have been synthesized by a templateless route via in-situ emulsion polymerization of aniline in aqueous DBSA solution. XRD patterns, UV-Visible Spectroscopy, and FTIR analysis confirm the formation of PANI and PANI-DBSA, whereas FESEM images revealed their elongated rod shaped morphology. The chloroform dispersion of synthesized PANI-DBSA was spin coated over prefabricated interdigitated Pt patterned glass substrate to realize porous gas sensing active layer. The sensor displays good response in 1-1200 ppm ammonia concentration range and can repeatedly detect 300 ppm of ammonia with response time of 6 s, recovery time of 37 s and relative response value of 9.57. Besides, its response was found to be linear for 1-50 ppm ammonia concentration with relative response per ppm value of 0.01675.
Sensors & Transducers, 2010
In present investigations polyaniline matrix was synthesized by oxidative polymerization (chemically synthesized). The polyaniline matrix was prepared on Si- substrate. The active layer of PANI as a sensor was fabricated with the help of spin-coating technique. The structural insight into the synthesized polyaniline matrix was sought by Fourier Transform Infrared (FTIR) spectroscopy. The mechanism of formation of polyaniline was also confirmed by UV spectroscopy. The electrical conductivity was measured by four probe method at room temperature. Ammonia gas sensing characteristics of the synthesized polyaniline matrix was studied by measuring the change in electrical resistance on exposure to ammonia gas at different concentrations from 100 to 500 ppm. The polyaniline matrix exhibits excellent sensing behavior for ammonia gas.
2020
The useful ammonia (NH3) gas sensor based on polyaniline (PANI) film as an active sensing layer. The PANI films prepared on a Glass substrate by a simple in-situ polymerization technique. In FTIR spectroscopy N-H and CH stretching observed at the 3400 /cm which confirms the functional group of PANI. In UV–Visible absorption spectrum of the synthesized PANI film extended tail at 800nm representing the conducting ES state of Polyaniline. Ammonia (NH3) gas-sensing properties of the films prepared at 0C conditions were examined at room temperature in the range of 10 to 100ppm.The room temperature functioning of the sensor is critical, which facilitates low-power operation and also enhances the life time of a sensor. The observed variation in resistance of PANI film corresponding to 10 ppm and 100 ppm of NH3 exposure. Furthermore, good reproducibility and long-term stability were also observed over a concentration range from 10 to 100 ppm. These results indicate that the PANI films on gl...
Sensors and Actuators B: Chemical, 2013
Polyaniline (PANI) doped with 5-sulfosalicylic acid (SSA) has been synthesized employing several techniques, viz. polymerization, Langmuir Blodgett (LB), spin-coating and electrodeposition. The influence of process variation on the structure, electrical conductivity and ammonia vapour sensing performance (response percentage and response time) has been investigated. The synthesized samples have been structurally characterized by transmission electron microscopy (TEM), UV-vis, and FTIR spectra. TEM analysis reveals formation of nanorods and nanospheres of PANI. Nanorods are formed for the samples synthesized by electrodeposition and LB technique whereas for the samples synthesized by polymerization and spin-coating, nanospheres are formed. Among these four different synthesized samples, the one deposited by LB technique exhibits highest conductivity due to the ordered molecular architecture. An exploration of variation of conductivity of these samples after exposure to ammonia reveals that the polymerized sample having highest surface to volume ratio exhibits fastest response (least response time), while the spin coated sample show sluggish response. The importance lies in the mapping between response percentages of different samples with the surface to volume ratio of the various nanostructures.
The Polyaniline films were synthesized by oxidative polymerization of aniline using ammonium peroxydisulfate on poly (methyl methacrylate) substrate in the presence of p-toluene sulphonic acid for the development of ammonia sensor. The synthesized polyaniline films were characterized by using UV-visible, FTIR, SEM and the electrical conductivity. The ammonia sensing behavior of the synthesized film was studied by indigenously developed computer controlled gas chamber. The synthesized PANI film shows excellent sensing behavior for 20, 100 and 250 ppm of ammonia.
Synthetic Metals, 2013
Accurate and fast detection of ammonia gas is a highly desirable requisite in environmental gas analysis, the automotive industry, the chemical industry and for medical applications. In this study a cost effective and portable electrochemical ammonia (NH 3) gas sensor is reported. The sensor was based on polyaniline (PANI) nanofibres employing the techniques of electrical impedance spectroscopy with frequency response analysis and amperometry. PANI is well known for its interaction with ammonia gas. This conducting polymer (PANI) of the semi-flexible rod polymer family, is unique due to its easy synthesis method, environmental stability, and simple doping/dedoping chemistry. PANI was synthesized and characterized by SEM, FTIR, XRD and AFM studies. The experimental data were used to explain, characterize and standardize the changes, upon exposure to ammonia gas, in the resistive and capacitative components set up in the PANI electrochemical cell. This nondestructive chemical-gas sensor was characterized by high sensitivity, a wide range of measured concentrations (0-20 ppm) in case of EIS and (2.5-20 ppm) in case of amperometry, reliability and reproducibility of the sensing data.
RSC Adv., 2015
New ammonia and amine sensing materials based on hybrid polyaniline/titanium dioxide nanocomposites were synthesized by a one-pot chemical polymerization. Particular attention was paid to the influence of TiO 2 nanoparticles and the surface active dopants on the structure-property relationship of the nanocomposites in terms of their morphology, composition, electrical and sensing properties. Dodecylbenzenesulfonic (DBSA) and lauryl sulfuric (LSA) acids were used as polyaniline dopants. The nanocomposites sensing properties were evaluated at different humidity levels when exposed to ammonia, methyl-and trimethylamine (0.2 ppm to 1 ppm). The materials demonstrated strong responses and high sensitivity to the gases with a quantification limit of 20 ppb for ammonia. The sensors are reversible and have short response times. However, the response magnitude depends on the dopant nature. The results were interpreted in terms of basicity and size of the analyte gas molecules.
Sensors and Actuators A: Physical, 2013
Silicon (Si)-nanopolyaniline (PAni) conducting platform has been electrochemically developed for the sensitive sensing of ammonia. The nano PAni films are formed through the assembly of nano granules of the polymer. The average height of the film is in the range of 50 nm. The electrical conductivity of the Si-PAni is influenced in the presence of ammonia. The response of this conductometric sensor is almost linear within 5-50 ppm of ammonia. The response and the recovery times are observed to be 10 and 60 s, respectively for 10 ppm of ammonia. The response time of the sensor for other concentrations (viz. 20, 30, 40, 50 and 60 ppm ammonia) is also in the range of 10 ± 2 s. However, the recovery of the sensor takes slightly longer time (70 ± 3 s) in case of higher concentrations (≥40 ppm) of ammonia.
Synthetic Metals, 2010
The composite thin films of polyaniline (Pani) with multiwall carbon nanotube (MWNT) and single wall carbon nanotube (SWNT) for hydrogen gas sensing application are presented in this paper. Polyaniline (Pani) was synthesized by chemical oxidative polymerization of aniline using ammonium persulfate in acidic medium. The SWNT and MWNT were doped in Pani in presence of champhor sulfonic acid (CSA) by solution mixing method. Thin films of CNT/Pani composites were prepared by spin coating method. Finally, the response of these composite films for hydrogen gas was evaluated by monitering the change in electrical resistance at room tempeature. It is observed that the SWNT/Pani and MWNT/Pani composite films show a higher response as compare to pure Pani. The structural and optical properties of these composite films have been characterised by X-ray diffraction (XRD) and UV–visible spectroscopy respectively. Surface morphology of these films has also been characterised by optical microscopy.
Sensors and Actuators B-chemical, 2001
Chemically synthesised acrylic acid doped polyaniline (PANI:AA) has been utilised as an ammonia vapour sensor in a broad range of concentrations, viz. 1±600 ppm. The response, in terms of decrease in dc electric resistance on exposure to ammonia was observed. The change in resistance, DR, is found to increase linearly with NH 3 concentration upto 58 ppm and saturates thereafter. The decrease in resistance has been explained on the basis of removal of proton from the free acrylic acid (AA) dopant by the ammonia molecules thereby rendering free conduction sites in the polymer matrix. These results are well supported by FTIR spectral analysis and the X-ray diffraction studies. The FTIR spectra show a remarkable increase in benzenoid and quinoid vibrations. Also, simultaneous appearance of ±COO À and ammonium ion vibrations is indicative of the interaction of ammonia molecules with acrylic acid. The degree of crystallinity was found to increase substantially upto 58 ppm concentration. # .in (A.A. Athawale). 0925-4005/01/$ ± see front matter # 2001 Elsevier Science B.V. All rights reserved. PII: S 0 9 2 5 -4 0 0 5 ( 0 1 ) 0 0 7 8 0 -8
Nanostructured samples of polyaniline (PANI), doped with inorganic bismuth nitrate (Bi(NO3)3), have been synthesized employing chemical oxidative polymerization and electrodeposition. The influence of the process variation on the structure, room temperature electrical conductivity and on ammonia vapour sensing performance (response percentage and response time) has been investigated. The synthesized samples have been structurally characterized by transmission electron microscopy (TEM) UV-VIS and Fourier transform infrared (FTIR) spectra. TEM analysis reveals formation of nanorods and nanospheres of PANI. Polymerization produces nanospheres of PANI and electrodeposition leads to formation of nanorod-like structures. The conductivity of the prepared samples were measured as a function of time after exposure to ammonia indicating that the polymerized sample exhibit fast response (least response time), while the electrodeposited samples show sluggish response. Thus response percentages ...
JOURNAL OF ADVANCES IN PHYSICS
The conductive layer of emeraldine base polyaniline (PANI) thin film coated on silicon has successfully tested for ammonia. The bulk PANI powder was synthesized by oxidative polymerization of aniline using ammonium peroxidisulfate in an acidic medium and dissolved in N-methyl pyrrolidone (NMP) for coating the thin film on Silicon using spin coater. FTIR, UVvisible, and SEM were used to characterize the PANI thin film. The electrical conductivity of the PANI films has been studied by measuring the change in electrical conductivity by Four Probe Set up on exposure to ammonia gas (NH3) at different concentrations from 100 ppm to 500 ppm. margin.
Nanostructured samples of polyaniline (PANI) doped with different dopants (organic and inorganic) have been synthesized employing polymerization and electrodeposition. The influence of nature of dopants(organic and inorganic) and process variation on the room temperature electrical conductivity and on ammonia vapour sensing performance (response percentage and response time) has been investigated. The synthesized samples have been structurally characterized by transmission electron microscopy (TEM) and fourier transform infrared (FTIR) spectra. Regardless of type of dopants, polymerization produces nanospheres of PANI and electrodeposition leads to formation of nanorod-like structures. Among all the synthesized samples, the organic doped electrodeposited sample exhibits highest conductivity. The conductivity of the prepared samples ware measured as a function of time after exposure to ammonia indicating that the polymerized samples (both for organic and inorganic dopants) exhibit fastest response (least response time), while the electrodeposited samples show sluggish response. Thus response percentages of different samples are found to depend on the nanostructures which vary with the nature of dopants and process of preparation.
Journal of Materials Science: Materials in Electronics, 2019
In the present study, we report a facile synthesis of polyaniline (PANI) thin films and its application for the sensitive and selective detection of ammonia (NH 3) gas. The branched nanofibers of PANI have been synthesized by in situ oxidative polymerization of aniline monomer with varying oxidant concentration followed by deposition of thin films on a glass substrate by a dip coating method. The deposited thin films were characterized for their structural, morphological, and compositional studies using X-ray diffraction (XRD), Field emission scanning electron microscopy (FE-SEM) and Fourier transform Raman spectroscopic (FT-Raman) techniques. The XRD patterns revealed that the synthesized films are semicrystalline in nature. FE-SEM images exhibit interconnected branched nanofibrous network of PANI. The average fiber diameter observed from FE-SEM images is ~ 45 nm. The gas sensing performance of PANI thin films was studied in terms of sensitivity, responserecovery time and selectivity for different concentration of NH 3 gas. It is observed that PANI thin film gas sensor shown selective response towards NH 3 gas even at a lowest concentration up to 10 ppm at room temperature. Thus, the developed PANI thin film sensor exhibited an admirable gas sensing performances at room temperature towards NH 3 with high sensitivity of 63.50% for 100 ppm of NH 3 gas.
In this work, the simple and inexpensive technique for the development of toxic gas(ammonia) sensor using conducting polymer films is described. The Polyaniline films were synthesized by of oxidative polymerization of aniline using ammonium peroxydisulfate on poly (methyl methacrylate) substrate. In the present investigation, HClO 4 (Perchloric acid) and PVA on PMMA substrate has been successfully synthesized PANI film by simple chemical polymerization technique. The synthesized Polyaniline films were characterized by using UV-visible, FTIR, SEM and the electrical conductivity. The ammonia sensing behaviour of the synthesized structure was studied by indigenously developed computer controlled gas chamber. The synthesized PANI structure shows excellent sensing behavior for 20-250 ppm of ammonia.
Sensors
Polyaniline (PANI) is a conducting polymer, widely used in gas-sensing applications. Due to its classification as a semiconductor, PANI is also used to detect reducing ammonia gas (NH3), which is a well-known and studied topic. However, easier, cheaper and more straightforward procedures for sensor fabrication are still the subject of much research. In the presented work, we describe a novel, more controllable, synthesis approach to creating NH3 PANI-based receptor elements. The PANI was electrochemically deposited via cyclic voltammetry (CV) on screen-printed electrodes (SPEs). The morphology, composition and surface of the deposited PANI layer on the Au electrode were characterised with electron microscopy, Fourier-transform infrared spectroscopy and profilometry. Prior to the gas-chamber measurement, the SPE was suitably modified by Au sputtering the individual connections between the three-electrode system, thus showing a feasible way of converting a conventional three-electrode...
DOAJ (DOAJ: Directory of Open Access Journals), 2011
PANi, prepared by oxidative chemical polymerization and TiO 2 , synthesized by sol gel method. The PANi/TiO 2 thin film sensors were prepared by spin coating technique. PANi/TiO 2 nanocomposites were characterized by XRD and SEM. The cross sensitivity of thin film sensor indicate that the sensor exhibit selectivity to ammonia (NH 3). The gas sensing measurements were carried out for different concentrations of NH 3. The gas sensing study revealed that the response value increases with increasing concentration of NH 3. Moreover, as concentration of NH 3 increases, the response time decreases while recovery time increases, which can be attributed to the varying adsorption and desorption rates of an ambient gas with increasing concentration.
Sensors and Actuators B: Chemical, 2017
We have successfully developed a simple and effective electrochemical way for making Pd-functionalized PANi nanowires (PANI/Pd-NPs) directly on interdigitated platinum microelectrode. As purpose to improve gas sensing specifications such as sensor response and response kinetics of PANI films, at room temperature without special heating equipment, the microstructure of the films consisting of PAN nanowires was controlled, but continued (continuing) to decorate with Pd nanoparticles then.
Sensors and Actuators B: Chemical, 2009
Thin films of tin oxide-intercalated polyaniline nanocomposite have been deposited at room temperature, through solution route technique. The as-grown films were studied for some of the useful physicochemical properties, making use of XRD, FTIR, SEM, etc. and optical methods. XRD studies showed peak broadening and the peak positions shift from standard values, indicating presence of tin oxide in nanoparticles form in the polyaniline (PANI) matrix. FTIR study shows presence of the Sn-O-Sn vibrational peak and characteristic vibrational peaks of PANI. Study of SEM micrograph revealed that the composite particles have irregular shape and size with micellar templates of PANI around them. AFM images show topographical features of the nanocomposite similar to SEM images but at higher resolution. Optical absorbance studies show shifting of the characteristics peaks for PANI, which may be due to presence of tin oxide in PANI matrix. On exposure to ammonia gas (100-500 ppm in air) at room temperature, it was found that the PANI film resistance increases, while that of the nanocomposite (PANI + SnO 2) film decreases from the respective unexposed value. These changes on removal of ammonia gas are reversible in nature, and the composite films showed good sensitivity with relatively faster response/recovery time.